Philosophical Investigations, reading it together. The next few sections mark what I take to be another change in theme, giving explicit attention to the nature of rules, which have periodically cropped up in the discussion so far, but not quite in so explicit a fashion as the next few parts. Zooming out again, so far, a breakdown of what's been covered might look like this:
§1-§27: Imperatives (block! slab!)
§28-§36: Demonstratives (this, that)
§37-§45: Names (Nothung, Mr. N.N.)
§46-§64: Linguistic Roles (Simples, Composites, and Iterations thereof)
§65-§80: Definitions and Boundaries
§81-88(?): Rules, Logic, and Idealization
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Anyway, lets tackle §81:
It's worth recalling some of what motivates the current discussion before digging into it, specifically, Witty's comment back in §65 that there is no 'general form of the proposition', and that one must look 'close up' in order to understand language. In this light, §81 and onwards is something like a critique of what happens when you do the opposite of this: a look at what happens when language is not looked at from 'close up', and instead treated in an 'ideal' sense.
Witty begins by comparing the use of language to games and "calculi with fixed rules", and notes that there is nothing necessary about any such comparison: language use can be compared to games, but this doesn't mean that it really 'is' or 'must be' such a game. Language-use has an autonomy from any such 'fixed calculi' at the end of the day, and cannot be reduced to them. Or, to put it sharply, there is an irreducible wedge between language and logic.
In saying this however, Witty also wants to stave off another misunderstanding that may follow from this: the idea that language is somehow then a degraded or less-perfect thing than logic. The basic idea is that logic if not an 'ideal language' of which specific instances of human language are lesser forms of. In saying this, Witty interestingly sheds light not only on language, but on logic as well: following (his understanding of) Ramsey, Witty understands logic to be a matter of construction, something 'made' and not 'found'.
Hence, in turn, the sharp distinction between the way in which 'natural science treats of a natural phenomenon', and logic, which deals with ideal constructions. This sharp distinction helps explain the reference to Ramsey at the beginning, in which logic is referred to as a 'normative science'. The idea being that something constructed must at every point be governed by some kind of imperative or rule which enables transitivity between propositions (this follows from that if...; think of axiomatic systems where every move must be justified according to the axioms which ground it). Note that 'normative' here must be understood in its formal and logic sense, and not its ethical and juridicial sense.
By contrast, natural phenomena do not participate in any such economies of inference, but instead economies of causes. I'm admittedly banking on a distinction treated in detail by Sellars on this (causes vs. reasons), but I think putting it in these terms - although not explicitly employed by Wittgenstein - is very useful in helping to understand the sharp distinctions at work in §81 (and I know I keep dragging it in, but in the remarks and lectures on Math, Witty continuously makes reference to the distinction between natural phenomena and ideal language and insists constantly just how important it is to keep the two apart).